
| 10.1002/cphc.202100748
http://scihub22266oqcxt.onion/10.1002/cphc.202100748
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Chemphyschem 2022 ; 23 (5): e202100748 Nephropedia Template TP
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Sodiation Of Hard Carbon: How Separating Enthalpy And Entropy Contributions Can Find Transitions Hidden In The Voltage Profile #MMPMID34859948Mercer MP; Affleck S; Gavilan-Arriazu EM; Zulke AA; Maughan PA; Trivedi S; Fichtner M; Reddy Munnangi A; Leiva EPM; Hoster HEChemphyschem 2022[Mar]; 23 (5): e202100748 PMID34859948show ga
Sodium-ion batteries (NIBs) utilize cheaper materials than lithium-ion batteries (LIBs) and can thus be used in larger scale applications. The preferred anode material is hard carbon, because sodium cannot be inserted into graphite. We apply experimental entropy profiling (EP), where the cell temperature is changed under open circuit conditions. EP has been used to characterize LIBs; here, we demonstrate the first application of EP to any NIB material. The voltage versus sodiation fraction curves (voltage profiles) of hard carbon lack clear features, consisting only of a slope and a plateau, making it difficult to clarify the structural features of hard carbon that could optimize cell performance. We find additional features through EP that are masked in the voltage profiles. We fit lattice gas models of hard carbon sodiation to experimental EP and system enthalpy, obtaining: 1. a theoretical maximum capacity, 2. interlayer versus pore filled sodium with state of charge.�
  
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